Synthesis and characterization of atomic layer deposited titanium nitride thin films on lithium titanate spinel powder as a lithium-ion battery anode |
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Authors: | Mark Q Snyder Svetlana A Trebukhova Boris Ravdel M Clayton Wheeler Joseph DiCarlo Carl P Tripp William J DeSisto |
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Affiliation: | 1. Department of Chemical and Biological Engineering, University of Maine, 5737 Jenness Hall, Orono, ME 04469, USA;2. Yardney Technical Products/Lithion Inc., Pawcatuck, CT 06379, USA;3. Laboratory for Surface Science and Technology (LASST), 5708 ESRB-Barrows, Orono, ME 04469, USA;4. Department of Chemistry, University of Maine, Orono, ME 04469, USA |
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Abstract: | Lithium titanate spinel (Li4Ti5O12, or LTS) is receiving consideration as a nanopowder anode material for use in lithium-ion batteries. LTS has more positive working potential than traditional graphite anodes, and it does not react with electrolyte components. However, the main drawback of LTS powder is its poor interparticle electronic conductance that reduces the high-rate ability of the electrode. To improve this we have coated the surface of the LTS powder with a titanium nitride layer by atomic layer deposition (ALD). In situ infrared spectroscopy studies were conducted to confirm the attachment of the titanium precursor. The nitrogen content of films was measured by total nitrogen content testing. Transmission electron microscopy (TEM) micrographs confirmed the formation of a thin titanium nitride film around LTS particles by ALD. Finally, lithium cells with electrodes made of original and modified LTS nanopowders were assembled and tested. |
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Keywords: | Lithium titanate spinel Lithium-ion batteries Atomic layer deposition Diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy Voltage profile Charge capacity |
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