| 线型聚苯乙烯支载手性咪唑烷酮的制备 |
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| 引用本文： | 林军,卢翠芬,陈祖兴,杨桂春.线型聚苯乙烯支载手性咪唑烷酮的制备[J].胶体与聚合物,2012,30(1):33-35. |
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| 作者姓名： | 林军 卢翠芬 陈祖兴 杨桂春 |
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| 作者单位： | 湖北大学化学化工学院 湖北武汉430062 |
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| 基金项目： | 湖北省自然科学基金重点项目(2010CDA019) |
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| 摘 要： | 以N-叔丁氧羰基-L-酪氨酸乙酯为原料,经系列反应制备(S)-4-4′-(对乙烯基苄氧基)苄基]-1-苯基-2-咪唑烷酮手性单体,用AIBN作引发剂,与苯乙烯溶液聚合制备线型聚苯乙烯支载的手性咪唑烷酮,用IR、1H-NMR、13C-NMR及元素分析对其结构进行表征,所得数据与其结构相吻合。
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| 关 键 词： | 线型聚苯乙烯 支载 手性咪唑烷酮 制备 |
Synthesis of Linear Polystyrene Supported Chiral Imidazolidinone |
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| LIN Jun
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LU Cuifen
,
CHEN Zuxing
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YANG Guichun.Synthesis of Linear Polystyrene Supported Chiral Imidazolidinone[J].Chinese Journal of Colloid and Polymer,2012,30(1):33-35. |
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| Authors: | LIN Jun LU Cuifen CHEN Zuxing YANG Guichun |
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| Affiliation: | (School of Chemistry and Chemical Engineering Hubei University Wuhan 430062) |
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| Abstract: | A chiarl imidazolidinone monomer was synthesized by using N-tert-butoxycarbonyl-Boc-L-tyrosine ethyl ester as initiating chiral material by seven reactions.Linear polystyrene supported imidazolidinone was obtained by the monomer copolymerized with styrene using AIBN as initiator.The product was characterized by IR,1H NMR,13C NMR and elemental analysis.The spectrum analytical result was consistent with the compound structure. |
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| Keywords: | Linear Polystyrene Supported Chiral Imidazolidinone Synthesis |
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