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| 2-甲基烯丙醇催化氧化为2-甲基烯丙醛的研究 | |
| 引用本文： | 邵戴妮,曹瑞伟,陈朝辉,吴美玲,夏燕华,邬希敏.2-甲基烯丙醇催化氧化为2-甲基烯丙醛的研究[J].广州化工,2012,40(21):91-92. |
| 作者姓名： | 邵戴妮 曹瑞伟 陈朝辉 吴美玲 夏燕华 邬希敏 |
| 作者单位： | 1. 绍兴文理学院化学化工学院,浙江绍兴,312000 2. 浙江医药股份有限公司新昌制药厂,浙江新昌,312500 3. 浙江医药股份有限公司维生素厂,浙江绍兴,312000 |
| 基金项目： | 绍兴文理学院大学生课题基金 |
| 摘 要： | 对2-甲基烯丙醇选择性催化氧化为2-甲基烯丙醛的体系进行了研究。实验表明,TEMPO、CuI、1,10-菲罗啉组成了一个稳定的络合体系,不但反应活化能降低,而且催化体系更加稳定,从而使反应速度和产率显著提高,为该体系的进一步研究提供了一定的理论参考。 |
| 关 键 词： | TEMPO CuI 1 10-菲罗啉 2-甲基烯丙醇 2-甲基烯丙醛 |
Study of Catalytic Oxidation of 2-methylallyl alcohol to 2-methylallyl aldehyde |
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| SHAO Dai-ni,CAO Rui-wei,CHEN Chao-hui,WU Mei-ling,XIA Yan-hua,WU Xi-min.Study of Catalytic Oxidation of 2-methylallyl alcohol to 2-methylallyl aldehyde[J].GuangZhou Chemical Industry and Technology,2012,40(21):91-92. | |
| Authors: | SHAO Dai-ni CAO Rui-wei CHEN Chao-hui WU Mei-ling XIA Yan-hua WU Xi-min |
| Affiliation: | 1 College of Chemistry and Chemical Engineering,Shaoxing University,Zhejiang Shaoxing 312000; 2 Zhejiang Medicine Co.,Ltd.,Xinchang Pharmaceutical Factory,Zhejiang Xinchang 312500; 3 Zhejiang Medicine Co.,Ltd.,Vitamin Factory,Zhejiang Shaoxing 312000,China) |
| Abstract: | Transformation of 2-methylallyl alcohol to 2-methylallyl aldehyde by collaborative catalytic oxidation system composed of TEMPO,CuI,1,10-Phenanthroline was studied.The experimental results showed that a stable complication system was formed,and not only the reaction activation energy reduced,but also the catalytic system was more stable,which led to the reaction accelerated and the yield increased significantly,and provided a certain theory reference to the further study of the system. |
| Keywords: | TEMPO CuI 1 10-Phenanthroline 2-methylallyl alcohol 2-methylallyl aldehyde |
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