Anionic ring opening polymerization of 1-silacyclopent-3-ene |
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| Authors: | Stephen Q Zhou Young Tae Park Georges Manuel William P Weber |
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| Affiliation: | (1) D.P. and K.B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661 Los Angeles, CA, USA |
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| Abstract: | Summary 1-Silacyclopent-3-ene (I) undergoes anionic ring opening polymerization catalyzed by methyllithium/HMPA to yield poly(1-sila-cis-pent-3-ene) (II). II was characterized by 1H, 13C, and 29Si NMR, GPC, TGA and elemental analysis. The low molecular weight of II permits end group analysis. Pyrolysis of II gives high char yields. These have been characterized by EDS. |
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