Fundamental Principles of Selective Heterogeneous Oxidation Catalysis |
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| Authors: | Grasselli Robert Karl |
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| Affiliation: | (1) Departments of Chemical Engineering and Materials Science, University of Delaware, Newark, DE 19716, USA. Institute of Physical Chemistry, University of Munich, Butenandtstrasse 5-13, D-81377 Munich, Germany |
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| Abstract: | Seven principles ( seven pillars ) underpinning selective heterogeneous oxidation catalysis, comprising lattice oxygen, metal-oxygen bond strength, host structure, redox, multifunctionality of active sites, site isolation, and phase cooperation are described. Their intended utilization towards a deeper understanding of metal oxide catalyst behavior and application towards catalyst design are indicated. |
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| Keywords: | lattice oxygen metal-oxygen bond host structure redox multifunctionality site isolation phase cooperation oxidation ammoxidation acrolein acrylonitrile molybdates antimonates |
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