| 钛硅分子筛混合溶剂洗涤再生的研究 |
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| 引用本文： | 王梅正,林民,朱斌.钛硅分子筛混合溶剂洗涤再生的研究[J].工业催化,2007,15(11):63-65. |
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| 作者姓名： | 王梅正 林民 朱斌 |
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| 作者单位： | 1.中国石化青岛石化有限责任公司公司，山东 青岛 266043；2.中国石化石油化工科学研究院，北京 100083 |
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| 基金项目： | 国家重点基础研究发展计划(973)项目(2006CB202508) |
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| 摘 要： | 研究了失活钛硅分子筛采用过氧化氢和甲醇溶剂混合洗涤的再生过程。通过正交实验，系统考察了再生温度、再生时间、过氧化氢与甲醇质量比和混合溶剂量四个因素对再生过程的影响，得到了再生的最佳工艺条件。在此条件下，反应30 min，环氧丙烷选择性为98.55%，环氧丙烷收率为26.35%，H2O2转化率为32.4%。
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| 关 键 词： | 钛硅分子筛 溶剂洗涤 再生 |
| 文章编号： | 1008-1143（2007）11-0063-03 |
| 收稿时间： | 2007-06-05 |
| 修稿时间： | 2007年6月5日 |
Regeneration of deactivated TS-1 zeolite via mixed solvent washing |
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| WANG Meizheng,LIN Min,ZHU Bin.Regeneration of deactivated TS-1 zeolite via mixed solvent washing[J].Industrial Catalysis,2007,15(11):63-65. |
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| Authors: | WANG Meizheng LIN Min ZHU Bin |
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| Affiliation: | 1.Sinopec Qingdao Petrochemical Corporation, Qingdao 266043, Shandong,China; 2.Sinopec Research Institute of Petroleum Processing, Beijing 100083, China |
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| Abstract: | The regeneration process for deactivated TS-1 zeolite using methanol hydrogen peroxide solvent was studied. The effects of temperature, time, hydrogen peroxide methanol ratio and mixed solvent amount were investigated by orthogonal experiment. The effects declined in the following sequence: temperature＞time＞hydrogen peroxide methanol ratio＞mixed solvent amount. The optimum regeneration condition was obtained as follows: 140 ℃，6 h，hydrogen peroxide 40 g. Selectivity to propylene epoxide of 98.55%, propylene epoxide yield of 26.35% and hydrogen peroxide conversion of 32.40% were obtained under the optimal condition after reaction for 30 min. |
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| Keywords: | TS-1 zeolite regeneration hydrogen peroxide mixed solvent washing |
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