| 丁—苯乳聚中不同引发体系的反应速度 |
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| 引用本文： | 焦书科,罗斌.丁—苯乳聚中不同引发体系的反应速度[J].弹性体,1993,3(2):1-7. |
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| 作者姓名： | 焦书科 罗斌 |
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| 作者单位： | 北京化工学院应用化学系 100029 |
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| 摘 要： | 本文以短周期(≤10小时)高转化(70±2％)E-SBR-1500的合成为目标,在对比不同氧化—还原引发剂聚合活性的基础上,研究了氯化剂/还原剂配比、电解质、乳化剂、硫醇和聚合温度对聚合速度的影响,为确定合成配方和加料方式提供了基础数据。
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| 关 键 词： | 引发剂 丁二烯 苯乙烯 乳液聚合 |
COPOLYMERIZATION RATE OF DIFFERENT REDOX SYSTEM IN EMULSION COPOLYMERIZATION OF BUTADIENE-STYRENE |
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| Luo Ein,Wu Mingguang,Yu Dingsheng and Jiao Shuke.COPOLYMERIZATION RATE OF DIFFERENT REDOX SYSTEM IN EMULSION COPOLYMERIZATION OF BUTADIENE-STYRENE[J].China Elastomerics,1993,3(2):1-7. |
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| Authors: | Luo Ein Wu Mingguang Yu Dingsheng and Jiao Shuke |
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| Abstract: | In order to increase the conversion of Bd-St within shorten period in the emulsion copolymerization of butadiene and styrene, the effect of the mole.ratio of Oxidant/Reducing agent,emulgent,the kinds of electrolytes,polymerization temperature and mercaptan on the copolymerization rate were investigated based on the polymerization activity of different Redox system. After that the fundamental data for polymerization recipe and feeding method of synthetic E-SBR-1500 was suggested. |
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| Keywords: | High-activity redox system Emulsion copolymerization of Bd-St Emulsion copolymerization rate of Bd-St Increasing the conversion of Bd-St |
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