| 含偶氮基卟啉大环衍生物的制备及表征 |
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| 引用本文： | 张茂峰,毛金玲,钟玲,王延敏.含偶氮基卟啉大环衍生物的制备及表征[J].中国材料科技与设备,2008,5(4):33-34. |
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| 作者姓名： | 张茂峰 毛金玲 钟玲 王延敏 |
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| 作者单位： | 山东科技大学材料科学与工程学院,山东青岛266510 |
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| 摘 要： | 文章介绍了有光、热敏感性能的四（4-重氮基苯基）卟啉及含有偶氮基团的卟啉衍生物的合成，用红外光谱，紫外光谱，飞行质谱等进行了结构表征，并对其光、热稳定性进行了研究。
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| 关 键 词： | 四(4-重氮基苯基)卟啉 偶氮基卟啉衍生物 重氮化反应 |
Synthesis and Characterization of Azo Containing Porphyrin |
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| ZHANG Mao-feng,MAO Jin-ling,ZHONG Ling,WANG Yan-min.Synthesis and Characterization of Azo Containing Porphyrin[J].Chinese Materials Science Technology & Equipment,2008,5(4):33-34. |
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| Authors: | ZHANG Mao-feng MAO Jin-ling ZHONG Ling WANG Yan-min |
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| Affiliation: | ( College of Material Science and Engineering, SUST, Shandong ,Qingdao, 266510,China) |
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| Abstract: | Tetra-（4-diazoniumbenzene） porphyrin （TDBP） was synthesized via diazo-reaetion of tetra-（4-aminobenzene） porphyrin （TABP）. From the analysis of MALDI-TOF Mass and FT-IR it was confirmed that the synthesized porphyrin derivative mainly consists of tetra-（4-diazoniumbenzene） porphyrin with trace tri-and di-substituted compounds. Its thermal-,photosensitive properties were also studied. |
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| Keywords: | Tetra-（4-diazoniumbenzene）porphyrin Azo porphyrin derivatives Diazo-reaction |
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