| 聚甲基环戊二烯基硅烷及其共聚物的合成与表征 |
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| 引用本文： | 邓建平,史保川,廖学巍.聚甲基环戊二烯基硅烷及其共聚物的合成与表征[J].有机硅材料,2001,15(6):1-5. |
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| 作者姓名： | 邓建平 史保川 廖学巍 |
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| 作者单位： | 南京师范大学化学与环境科学学院, |
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| 基金项目： | 江苏省科委和教委自然科学基金资助课题,江苏省高校省级重点实验室资助,南京市科委重点基金资助. |
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| 摘 要： | 用钠试剂法合成了甲基环戊二烯基二氯硅烷，采用钠缩合法将其均聚，并分别与二甲基二氯硅烷、二苯基二氯硅烷、甲基苯基二氯硅烷及甲基正丁基二氯硅烷进行共聚反应，合成了5种聚硅烷。并用IR、UV、^1H NMR、GPC和荧光光谱对它们进行了表征。
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| 关 键 词： | 甲基环戊二烯基二氯硅烷 钠缩合法 聚甲基环戊二烯基硅烷 聚硅烷 钠试剂 合成 表征 |
| 修稿时间： | 2001年8月8日 |
Synthesis and Characterization of Polymethylcyclopentadienylsilane and Its Copolysilane |
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| Deng Jianping,Shi Baochuan,Liao Xuewei.Synthesis and Characterization of Polymethylcyclopentadienylsilane and Its Copolysilane[J].Silicone Material,2001,15(6):1-5. |
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| Authors: | Deng Jianping Shi Baochuan Liao Xuewei |
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| Abstract: | s:Methylcyclopentadienyldichlorosilane was synthesized by means of Sodium reagent.Polymethylcyclopentadienylsilane,poly(dimethylsilane-co-methylcyclopentadienylsilane),poly(diphenylsilane-co-methylcyclopentadienylsilane),poly(methylphenylsilane-co-methylcyclopentadienylsilane) and poly(methylbutylsilane-co-methylcyclopentadienylsilane) were synthesized by the method of the Sodium condensation with methylcyclopentadienyldichlorosilane and dimethyldichlorosilane,diphenyldichlorosilane,methylphenyldichlorosilane, methylbutyldichlorosilane.The structures of the polymers were characterized by means of UV, 1H NMR,IR and GPC. |
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| Keywords: | methylcyclopentadienyldichlorosilane Sodium reductive coupling polymethylcyclopentadienylsilane polysilane Sodium reagent |
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