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Synthesis,structural, thermal and optical properties of TeO2–Bi2O3–GeO2–Li2O glasses
Affiliation:1. Institute of Mineralogy and Crystallography, Bulgarian Academy of Sciences, Building 107, 1113 Sofia, Bulgaria;2. Institute of Physical Chemistry, Bulgarian Academy of Sciences, Acad. Georgi Bonchev str., Building 11, Sofia 1113, Bulgaria;3. Institute of Solid State Physics, Acad. G. Nadjakov, Bulgarian Academy of Sciences, 1784 Sofia, Bulgaria;1. Laboratory of Infrared Material and Devices, Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China;2. Key Laboratory of Photoelectric Materials and Devices of Zhejiang Province, Ningbo 315211, China;3. Key Laboratory of Chemical Lasers, Chinese Academy of Sciences/Dalian Institute of Chemical Physics, Dalian 116023, China;1. Key Laboratory of Transparent and Opto-functional Advanced Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai, 200050, China;2. Analysis and Testing Center for Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China;3. Institute of Applied Electronics, China Academy of Engineering Physics, Mianyang, Sichuan, 621900, China;4. Key Laboratory Science and Technology on High Energy Laser, China Academy of Engineering Physics, Mianyang, Sichuan, 621900, China;5. Department of Physics, Shanghai Normal University, Shanghai, 200234, China;1. Department of Physics, University of the Free State, P.O. Box 339, Bloemfontein, ZA9300, South Africa;2. Department of Physics, University of South Africa, P.O. Box 392, Pretoria, ZA0003, South Africa;1. Department of Material Science and Engineering, Izmir Institute of Technology, Izmir, Turkey;2. Vestel Electronics, LED Lighting R&D Department, O.S.B., 45030, Manisa, Turkey;1. New Technologies – Research Centre, University of West Bohemia, Univerzitni 8, 306 14 Pilsen, Czech Republic;2. Semiconductor Photonics and Integrated Lightwave System (SPILS), Tun Abdul Razak Laser Lab Laboratory (TAReL), School of Microelectronic Engineering, Universiti Malaysia Perlis (UniMAP), Pauh Putra Main Campus, Jalan Arau-Changlun, 02600 Arau, Perlis, Malaysia;3. Center of Excellence Geopolymer and Green Technology, School of Material Engineering, University Malaysia Perlis, 01007 Kangar, Perlis, Malaysia;4. Department of Electrical and Electronic Engineering, Faculty of Engineering, National Defence University of Malaysia (UPNM), Kem Sungai Besi, 57000 Kuala Lumpur, Malaysia;5. Department of Physics and Astronomy, College of Science, P.O. Box 2455, King Saud University, Riyadh 11451, Saudi Arabia;6. Department of Instrumentation and Control Engineering, Faculty of Mechanical Engineering, CTU in Prague, Technicka 4, 166 07 Prague 6, Czech Republic
Abstract:In this study, synthesis and characterization of novel quaternary tellurite glass system TeO2–Bi2O3–GeO2–Li2O is presented. The compositions include TeO2 and GeO2 as glass formers while different proportion of Bi2O3 and Li2O act as network modifiers. Differential thermal analysis, X-ray diffraction, scanning electron microscopy energy dispersive X-ray spectroscopy, laser ablation inductively coupled plasma mass spectrometry, UV–Vis and Raman spectroscopy are applied to study the structural, thermal and optical properties of the studied glasses. Obtained glasses possess a relatively low glass transition temperature (around 300 °C) if compared to other tellurite glasses, show good thermal transparency in the visible and near infra-red (from 2.4 to 0.4 μm) and can double the frequency of laser light from its original wavelength of 1064 nm to its second-harmonic at 532 nm (i.e. second harmonic generation).
Keywords:Tellurite glasses  XRD  Raman  SHG
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