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Experimental investigation of the fire extinguishing capability of ferrocene-containing water mist
Affiliation:1. Department of Materials Science and Chemical Engineering, Faculty of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan;2. Department of Safety Management, Faculty of Environmental and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan;1. Department of Chemical Engineering, Queen''s University, Kingston, ON, K7L 3N6, Canada;2. Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan;1. School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China;2. Institute of Industrial Technology of Guangzhou and Chinese Academy of Science, Guangzhou 511458, China;3. Department of Civil and Architectural Engineering, City University of Hong Kong, Kowloon, Hong Kong, China
Abstract:This study focuses on the fire-suppression capabilities and corrosive properties of ferrocene dispersions. The motivation behind the present study was to develop a high-performance, phosphorus-free fire suppressant. Aqueous dispersions containing micron-sized ferrocene particles and surfactants were prepared using sonication techniques. In this study, Triton X-100 (TX), Noigen TDS-80 (NT), Tween 60 (T60), and Tween 80 (T80) were used as surfactants. Suppression experiments involving pool fires clearly indicated that aqueous ferrocene dispersions containing TX and micron-sized ferrocene with a d50=16.9 μm exhibit shorter extinguishing times than a conventional wet chemical. Corrosion trials using steel plates immersed in ferrocene dispersions containing TX confirmed that there was no pitting corrosion, implying that ferrocene dispersions containing TX do not present a corrosion risk.
Keywords:Ferrocene powder  Fire suppression  Aqueous dispersion  Water mist  Additive  Extinguishing time  Fire-extinguishing agent  Corrosion
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