Zirconia-based luminescent organic-inorganic hybrid materials with ternary europium (III) complexes bonded |
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| Affiliation: | 1. Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, PR China;2. China Tobacco Henan Industrial Co. Ltd., Zhengzhou, Henan 450000, PR China |
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| Abstract: | In this work, a novel red-emitting organic-inorganic hybrid material with europium (III) lanthanide β-diketonate complexes linked to a zirconia was reported, which was realized by adduct formation with zirconia-tethered terpyridine moieties. Luminescence enhancement of the hybrid material has been observed compared with pure Eu(tta)3·2H2O. Transparent and strongly luminescent thin films based on PMMA were also prepared at room temperature, which are highly luminescent under UV-light irradiation and possess a promising prospect in the area of optics. |
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| Keywords: | Zirconia Europium (III) complex Hybrid materials Transparent film |
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