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Biocompatible nanofilm coating by magneto-luminous polymerization of methane
Authors:Hirotsugu Yasuda  Loic Ledernez  Fethi Olcaytug  Gregory Dame  Michael Bergmann
Affiliation:1. Center for Surface Science & Plasma Technology, Department of Chemical Engineering, University of Missouri, Columbia, MO, USA;2. Department of Microsystems Engineering, Albert-Ludwigs-University of Freiburg, Germany
Abstract:Coating is uniquely feasible means to impart biocompatibility to artificial materials to be used in biology and medicine, because a totally different surface-state could be created. However, it is necessary to understand factors that control “biocompatibility” first. The examination of molecular level factors involved in interfacial interaction revealed that the best surface-state for biocompatibility should contain no chemical functional group. Such a surface-state cannot be created by conventional chemical means, and application of conventional coating could be used in rather limited cases only. Magneto-luminous polymerization of methane yields nanofilm of amorphous carbon, which seems to be the closest to the ideal non-interacting surface. Fundamental factors involved in interactions of polymer surface with surrounding medium, and mechanisms how magneto-luminous polymerization coating yields amorphous carbon nanofilm, which has the least interfacial interaction capability, are described in this paper.
Keywords:Interfacial interaction   Surface-state   Interfacial Configuration of Molecules   Luminous gas-phase   Magneto-luminous gas-phase   Dissociation glow   Ionization glow   Gas-phase-breakdown of organic molecule
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