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In2O3:Ga and In2O3:P-based one-electrode gas sensors: Comparative study
Affiliation:1. School of Material Science and Engineering, Gwangju Institute of Science and Technology, 261 Cheomdan-gwagiro, Buk-gu 500-712 Gwangju, Republic of Korea;2. Department of Physics and Engineering, State University of Moldova, Chisinau, Republic of Moldova;3. Laboratory of Physics of Nanostructures, State University of Moldova, Chisinau, Republic of Moldova;4. Division of Maritime Transportation System, Mokpo National Maritime University, Mokpo, Republic of Korea;5. Innovatsensor Ltd., Minsk, Belarus;1. School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243002, PR China;2. Department of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong;1. Hunan Key Laboratory of Micro–Nano Energy Materials and Devices, Xiangtan University, Hunan 411105, PR China;2. Laboratory for Quantum Engineering Micro–Nano Energy Technology, School of Physics and Optoelectronics, Xiangtan University, Hunan 411105, PR China;1. Escola Técnica de Saúde, Universidade Federal da Paraíba, Cidade Universitária, João Pessoa CEP 58051-900, PB, Brazil;2. Departamento de Engenharia de Materiais, Universidade Federal de Campina Grande, Av. Aprígio Veloso 882, Catolé, Campina Grande CEP 58 429-900, PB, Brazil;3. Departamento de Engenharia de Materiais, Universidade Federal da Paraíba, Cidade Universitária, João Pessoa CEP 58051-900, PB, Brazil;1. Department of Materials Science and Engineering, National Cheng Kung University, Tainan City 70101, Taiwan;2. Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan City 70101, Taiwan;3. Center for Micro/Nano Science and Technology, National Cheng Kung University, Tainan City 70101, Taiwan;1. College of Logistics Engineering, Shanghai Maritime University, Shanghai 201306, China;2. Institute of Marine Materials Science and Engineering, College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
Abstract:Gas sensing characteristics of one-electrode sensors based on the In2O3 ceramics doped by gallium and phosphorus have been discussed. In2O3-based ceramic was prepared by sol–gel technology. Ozone, CO, CH4 and H2 were used as tested gases. The doping concentration effect on the sensor parameters such as magnitude of response, operating temperature, response and recovery times, sensitivity to the air humidity, and selectivity have been analyzed. It was shown that In2O3 doping by Ga and P could be used for the sensor performance optimization. It was assumed that the appearance of the second phase (InPO4 and Ga2O3) and the change of structural parameters, taking place during doping process, were the main factors controlling the change of operating characteristics in In2O3:P and In2O3:Ga-based sensors.
Keywords:Ceramics  Composite materials  Microporous materials  Interfaces  Electrical characterization
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