| 金属络合染料酸性黑ACE的合成 |
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| 引用本文： | 孙桂春. 金属络合染料酸性黑ACE的合成[J]. 染料与染色, 2014, 0(6): 19-22 |
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| 作者姓名： | 孙桂春 |
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| 作者单位： | 青岛科技大学化学与分子工程学院 |
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| 摘 要： | 2-氨基-4-硝基苯酚重氮化后,分别在酸性和碱性条件下与N-苯基-2-氨基-5-萘酚-7-磺酸偶合,得到偶氮物A和偶氮物B;6-硝基-1,2,4-酸氧体与2-萘酚偶合得到偶氮物C;偶氮物C和氧化铬络合反应得到络合物D;络合物D再与偶氮物A、偶氮物B在碱性条件下反应得到黑色非对称1∶2金属络合染料（酸性黑ACE）。本文介绍了该染料的化学结构及合成方法。
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| 关 键 词： | 酸性黑 重氮化 偶合 金属络合 |
Synthesis of Metal Complex Dye Acid Black ACE |
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| SUN Gui-chun. Synthesis of Metal Complex Dye Acid Black ACE[J]. Ranliao yu Ranse, 2014, 0(6): 19-22 |
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| Authors: | SUN Gui-chun |
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| Affiliation: | SUN Gui-chun;The Institute of Chemistry and Molecular Engineering,Qingdao University of Science and Technology; |
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| Abstract: | 2-Amino-4-nitrophenol was diazotized and coupled with N-phenyl-2-amino-5-naphthol-7-sulfonic acid in acidic or alkaline conditions,azo compound A and azo compound B were obtained,respectively. 6-Nitro-1 2 4-diazo acid coupled with β-naphthol,and azo compound C was dotained,compound C reacted with chromium oxide to afford a complex D. Then the black asymmetric 1 ∶ 2metal complex dye（ Acid Black ACE） was obtained by the reaction of D with A and B in alkaline conditions. The structure and synthesis of Acid Black ACE was discussed. |
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| Keywords: | acid black diazotization coupling compound metal complex |
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