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Piezoelectric properties of Pb(Zr,Ti)O3-Pb(Ni,Nb)O3 ceramics and their application in energy harvesters
Affiliation:1. Department of Nano Bio Information Technology, KU-KIST Graduate School of Converging Science and Technology, Korea University, 141 Anam-ro, Seongbuk-gu, Seoul, 02841, Republic of Korea;2. Department of Materials Science and Engineering, Korea University, 141 Anam-ro, Seongbuk-gu, Seoul, 02841, Republic of Korea;3. Electronic Materials and Device Research Center, Korea Electronics Technology Institute, 25, Saenari-ro, Bundang-gu, Seongnam-si, Gyeonggi-do, 13509, Republic of Korea;4. Center for Electronic Materials, Korea Institute of Science and Technology (KIST), Seoul, 02791, Republic of Korea;1. Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China;2. School of Material Science and Engineering, University of Jinan, Jinan 250022, China;3. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201204, China;1. School of Advanced Materials and Nanotechnology, Xidian University, Xi’an 710071, China;2. Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education & International Center for Dielectric Research, Xi’an Jiaotong University, Xi’an 710049, China;1. School of Materials Science and Engineering, Ulsan National Institute of Science and Technology (UNIST), 50, UNIST-gil, Ulsan 44919, Republic of Korea;2. Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul, 02841, Republic of Korea;3. Materials Analysis & Evaluation Department, Korea Institute of Materials Science (KIMS), 797, Changwondaero, Seongsan, Changwon, Gyeongnam, 51508, Republic of Korea;1. Department of Materials Science and Engineering, Korea University, Anam-dong 5-ga, Seongbuk-gu, Seoul 136-701, Republic of Korea;2. KU-KIST Graduate School of Conversing Science and Technology, Korea University, Seoul 136-701, Republic of Korea;3. Functional Ceramics Department, Korea Institute of Materials Science, 797 Changwondaero, Seongsan-gu, Changwon, Gyeongnam 642-831, Republic of Korea;4. Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Ulju-gun, Ulsan 689-798, Republic of Korea
Abstract:The piezoelectric properties of (1-x-y)PbZrO3-xPbTiO3-yPb(Ni1/3Nb2/3)O3 ceramics were investigated. Specimens with a large Pb(Ni1/3Nb2/3)O3 content, which have compositions close to the triple point, show small g33 and d33 × g33 values because of their large εT330. These values increased with a decrease in y (amount of Pb(Ni1/3Nb2/3)O3) and the specimen with x = 0.39 and y = 0.29 showed the largest g33 of 43 × 10−3 V·m/N and d33 × g33 of 25.2 × 10−12 m2/N. Cantilever-type energy harvesters were fabricated using specimens with 0.38  x  0.41 and y = 0.29. The output power densities of the energy harvesters were related to the d31 × g31 × k312 value of the piezoelectric ceramics. The energy harvester fabricated using a specimen with x = 0.39 and y = 0.29, which has a maximum d31 × g31 × k312 value, showed the maximum output power density of 1.01 mW/cm3.
Keywords:PZT-PNN  MPB  Piezoelectric energy harvester
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