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膨润土/丙烯酸聚合物吸水保水剂合成及性能研究
引用本文:冯启明,王维清,李瑾丽.膨润土/丙烯酸聚合物吸水保水剂合成及性能研究[J].非金属矿,2009,32(6).
作者姓名:冯启明  王维清  李瑾丽
作者单位:西南科技大学环境与资源学院,四川绵阳,621010
基金项目:国家自然科学基金资助项目 
摘    要:对膨润土/丙烯酸聚合物复合吸水保水剂研究结果表明,膨润土/丙烯酸吸水保水剂的最佳制备条件为:交联剂、膨润土、引发剂用量分别占单体质量的0.05%、15%、0.45%,反应温度为75℃,中和度为90%;在最佳条件下制备的膨润土/丙烯酸吸水保水剂的饱和吸蒸馏水倍率最高为796g/g;保水剂在室温下(25℃,湿度为77%)24h的水分蒸发量小于9%,而在60℃的水浴锅中10h水分蒸发99.72%;在转速4000r/min下离心10min保水率为57.4%,不同离心转速下,保水能力差异较小,该保水剂有较好的吸水保水性能,可广泛用于荒漠治理.

关 键 词:膨润土  丙烯酸聚合物  吸水保水剂

Synthesis and Propertyies of Bentonite/Acrylic Resin Water-Absorbent & Retaining Agent
Feng Qiming,Wang Weiqing,Li Jinli.Synthesis and Propertyies of Bentonite/Acrylic Resin Water-Absorbent & Retaining Agent[J].Non-metallic Mines,2009,32(6).
Authors:Feng Qiming  Wang Weiqing  Li Jinli
Affiliation:Feng Qiming Wang Weiqing Li Jinli ( College of Environment & Resources,South West University of Science & Technology,Mianyang,Sichuan 621010 )
Abstract:The research results of bentonite/acrylic resin water-absorbent & retaining agent show that the best preparation conditions are as follows: the amount of cross-linking agent, bentonite and initiator, accounting for 0.05%, 15%, 0.45% of the monomer mass, respectively. The reaction temperature is 75℃, and the neutralization degree of 90%. Water-absorbent & retaining agent has swelling capacity 796g/g in distilled water. At room temperature (25℃, relative humidity of 77%), 24 hours water evaporation quantity is less than 9%, and in 60℃ water-bath, 10 hours water evaporation quantity is 99.72%. In the centrifugation speed of 4000 r/min, 10min the water-retention rate is 57.4%.With different centrifugal speeds, there are smaller differences in water-retention capacity. Water retaining agent has good capacity of water-absorb & holding, it can be widely applied to harness hungriness.
Keywords:bentonite  acrylic resin polymer  water-absorbent & retaining agent
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