High temperature oxidation and ignition of some metallic materials in fluorine |
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Authors: | V I Bolobov P F Drozhzhin V G Nechaeva |
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Affiliation: | (1) Russian Scientific Center “Applied Chemistry”, 197198 St. Petersburg |
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Abstract: | When 3-mm-diameter cylindrical samples are heated by direct passage of an electric current through them, it is observed that
titanium, molybdenum, tungsten-niobium alloy, nickel, iron, carbon steel, and stainless steel in gaseous fluorine (p=0.2 MPa) ignite through a thermal explosion mechanism, while copper, its alloys, and aluminum ignite when the melting point
of the fluoride film is reached. The critical ignition temperatures of these materials are established. Experimental data
on the high temperature oxidation kinetics are used to calculate the pertinent parameters of the Arrhenius for the preignition
interaction of the steels and nickel with fluorine.
Translated fromFizika Goreniya i Vzryva, Vol. 34, No. 4, pp. 34–42, July–August 1998. |
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