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低共熔溶剂与偶联剂协同改性白炭黑对胎面胶性能的影响
引用本文:杨浩,王晨露,武姝妍,杜爱华.低共熔溶剂与偶联剂协同改性白炭黑对胎面胶性能的影响[J].合成橡胶工业,2022,0(1):60-64.
作者姓名:杨浩  王晨露  武姝妍  杜爱华
作者单位:青岛科技大学 高分子科学与工程学院, 山东 青岛 266042
摘    要:研究了硅烷偶联剂(TESPT)与低共熔溶剂(DES)协同改性白炭黑对作为胎面胶的天然橡胶复合材料性能的影响.用傅里叶变换红外光谱分析了 TESPT和DES与白炭黑之间的相互作用,用橡胶加工分析仪和扫描电镜分析了白炭黑之间的相互作用,并测试了复合材料的硫化特性、力学性能和耐磨性,通过动态力学分析仪考察了其滚动阻力和抗湿滑...

关 键 词:低共熔溶剂  偶联剂  白炭黑  改性  天然橡胶  损耗因子  胎面胶

Effect of co-modification of silica with deep eutectic solvent and coupling agent on properties of tread compound
YANG Hao,WANG Chen-lu,WU Shu-yan,DU Ai-hua.Effect of co-modification of silica with deep eutectic solvent and coupling agent on properties of tread compound[J].China Synthetic Rubber Industry,2022,0(1):60-64.
Authors:YANG Hao  WANG Chen-lu  WU Shu-yan  DU Ai-hua
Affiliation:School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
Abstract:The effect of silica modified by silane coupling agent (TESPT) and deep eutectic solvent (DES) on the properties of natural rubber (NR) composites as tread rubber was studied. The interaction between TESPT, DES and silica was analyzed by Fourier transform infrared spectroscopy, the interaction between silica and silica was analyzed by rubber processing analyzer and scanning electron microscope, the curing characteristics, mechanical properties and wear resistance of the composites were determined, and the rolling resistance and wet skid resistance were investigated by dynamic mechanical analyzer. The results showed that the synergistic modification of TESPT and DES could improve the dispersion of silica in NR, increase the vulcanization rate, improve the mechanical properties and wear resistance of the composites, and reduce the rolling resistance. When the amounts of TESPT and DES were 1 phr (mass) respectively, the NR composites had lower rolling resistance and better wet skid resistance.
Keywords:deep eutectic solvent  coupling agent  silica  modification  natural rubber  dynamic mechanical property  tread compound
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