Stable pattern and standing wave formation in a simple isothermal cubic autocatalytic reaction scheme |
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Authors: | R. Hill J. H. Merkin D. J. Needham |
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Affiliation: | (1) Department of Applied Mathematics, University of Leeds, LS2 9JT Leeds, UK;(2) School of Mathematics, University of East Anglia, NR4 7TJ Norwich, UK |
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Abstract: | The formation of stable patterns is considered in a reaction-diffusion system based on the cubic autocatalator, A+2B 3B, B C, with the reaction taking place within a closed region, the reactant A being replenished by the slow decay of precursor P via the reaction P A. The linear stability of the spatially uniform Steady state % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaamaabmGabaGaamyyaiaacYcacaWGIbaacaGLOaGaayzkaaGaeyyp% a0ZaaeWaceaacqaH8oqBdaahaaWcbeqaaiabgkHiTiaaigdaaaGcca% GGSaGaeqiVd0gacaGLOaGaayzkaaaaaa!48C3![left( {a,b} right) = left( {mu ^{ - 1} ,mu } right)], where a and b are the dimensionless concentrations of reactant A and autocatalyst B and is a parameter representing the initial concentration of the precursor P, is discussed first. It is shown that a necessary condition for the bifurcation of this steady state to stable, spatially non-uniform, solutions (patterns) is that the parameter % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiaadseacqGH8aapcaaIZaGaeyOeI0IaaGOmamaakaaabaGaaGOm% aaWcbeaaaaa!4139![D < 3 - 2sqrt 2 ] where D=Db/Da (Da and Db are the diffusion coefficients of chemical species A and B respectively). The values of at which these bifurcations occur are derived in terms of D and (a parameter reflecting the size of the system). Further information about the nature of the spatially non-uniform solutions close to their bifurcation points is obtained from a weakly nonlinear analysis. This reveals that both supercritical and subcritical bifurcations are possible. The bifurcation branches are then followed numerically using a path-following method, with as the bifurcation parameter, for representative values of D and . It is found that the stable patterns can lose stability through supercritical Hopf bifurcations and these stable, temporally periodic, spatially non-uniform solutions are also followed numerically. |
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