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Coinage Metals in the Nanometer Length Scale
Authors:Tarasankar Pal
Affiliation:  a Department of Chemistry, Indian Institute of Technology, Kharagpur, India
Abstract:Cetylpyridinium chloride (CPC)-stabilized gold organosol in toluene has been prepared by using a two-phase (water-toluene) extraction of AuCl4- followed by its reduction with sodium borohydride in the presence of the surfactant, CPC. The surfactant-stabilized gold nanoparticles were exploited to examine their optical properties when exposed to various solvent systems by measuring the changes in the localized surface plasmon resonance (LSPR) spectrum.
Keywords:Coinage metals  Colloid  Coordinatively unsaturated  Charge-transfer interaction  Interface  Localized surface plasma resonance  Metal-to-ligand charge-transfer band  Nanoparticles  Nucleophiles  Nonbonding electrons  Organosol  Optical properties  Refractive index  Surface complexation process  Surfactant
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