In Situ Synthesis of Graphene-Coated Silicon Monoxide Anodes from Coal-Derived Humic Acid for High-Performance Lithium-Ion Batteries |
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Authors: | Shuai Xu Jigang Zhou Jian Wang Sameera Pathiranage Nuri Oncel Pushparaj Robert Ilango Xin Zhang Michael Mann Xiaodong Hou |
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Affiliation: | 1. Institute for Energy Studies, University of North Dakota, Grand Forks, ND, 58202 USA;2. Canadian Light Source Inc., Saskatoon, S7N 2V3 Canada;3. Department of Physics & Astrophysics, University of North Dakota, Grand Forks, ND, 58202 USA |
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Abstract: | Silicon monoxide (SiO) is attaining extensive interest amongst silicon-based materials due to its high capacity and long cycle life; however, its low intrinsic electrical conductivity and poor coulombic efficiency strictly limit its commercial applications. Here low-cost coal-derived humic acid is used as a feedstock to synthesize in situ graphene-coated disproportionated SiO (D-SiO@G) anode with a facile method. HR-TEM and XRD confirm the well-coated graphene layers on a SiO surface. Scanning transmission X-ray microscopy and X-ray absorption near-edge structure spectra analysis indicate that the graphene coating effectively hinders the side-reactions between the electrolyte and SiO particles. As a result, the D-SiO@G anode presents an initial discharge capacity of 1937.6 mAh g−1 at 0.1 A g−1 and an initial coulombic efficiency of 78.2%. High reversible capacity (1023 mAh g−1 at 2.0 A g−1), excellent cycling performance (72.4% capacity retention after 500 cycles at 2.0 A g−1), and rate capability (774 mAh g−1 at 5 A g−1) results are substantial. Full coin cells assembled with LiFePO4 electrodes and D-SiO@G electrodes display impressive rate performance. These results indicate promising potential for practical use in high-performance lithium-ion batteries. |
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Keywords: | anodes graphene coating humic acid lithium-ion batteries silicon monoxide |
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