Efficient Visible-Light Driven Photothermal Conversion of CO2 to Methane by Nickel Nanoparticles Supported on Barium Titanate |
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Authors: | Diego Mateo Natalia Morlanes Partha Maity Genrikh Shterk Omar F. Mohammed Jorge Gascon |
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Affiliation: | 1. KAUST Catalysis Center (KCC), Advanced Catalytic Materials, King Abdullah University of Science and Technology, Thuwal, 23955-6900 Saudi Arabia;2. KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology, Thuwal, 23955-6900 Saudi Arabia |
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Abstract: | Solar-driven methanation represents a potentially cost-efficient and environmentally friendly route for the direct hydrogenation of CO2. Recently, photothermal catalysis, which involves the combination of both photochemical and thermochemical pathways, has emerged as a promising strategy for the production of solar fuels. For a photothermal catalyst to efficiently convert CO2 under illumination, in the absence of external heating, effective light harvesting, an excellent photothermal conversion and efficient active sites are required. Here, a new composite catalyst consisting of Ni nanoparticles supported on barium titanate that, under optimal reaction conditions, is able to hydrogenate CO2 to CH4 at nearly 100% selectivity with production rates as high as 103.7 mmol g–1 h–1 under both UV–visible and visible irradiation (production rate: 40.3 mmol g−1 h–1) is reported. Mechanistic studies suggest that reaction mostly proceeds through a nonthermal hot-electron-driven pathway, with a smaller thermal contribution. |
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Keywords: | carbon dioxide methanation photothermal catalysis solar fuels |
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