Photonic Vitrimer Elastomer with Self-Healing,High Toughness,Mechanochromism, and Excellent Durability based on Dynamic Covalent Bond |
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Authors: | Wenbin Niu Xianfei Cao Yunpeng Wang Bowen Yao Yusen Zhao Jie Cheng Suli Wu Shufen Zhang Ximin He |
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Affiliation: | 1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, West Campus, 2 Linggong Rd., Dalian, 116024 China;2. Department of Materials Science and Engineering, University of California, Los Angeles, CA, 90095 USA |
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Abstract: | Vitrimers, with their unique dynamic covalent bonds, possess attractive self-healability and mechanical robustness, providing an intriguing opportunity to construct functional soft materials. However, their potential for function recovery, especially optical function, is underexplored. Harnessing the synergistic effect of photonic crystals and vitrimers, a novel photonic vitrimer with light regulating and self-healing capabilities is presented. The resulting photonic vitrimer exhibits a large tensile strain (>1000%), high toughness (21.2 kJ m−3), bright structural color, and mechanochromism. Notably, the structural color remains constant even after 10 000 stretching/releasing cycles, showing superior mechanical stability, creep-resistance, and excellent durability. More importantly, the exchange of dynamic covalent bonds imparts the photonic vitrimer with a self-healing ability (>95% efficiency), enabling the recovery of its optical function. Benefiting from the above merits, the photonic vitrimer has been successfully used as a sensor for human motion detection, which demonstrates visualized interactive sensibility even after self-repairing. This material design provides a general strategy for optical functionalization of vitrimers. The photonic vitrimer elastomers present great potential as resilient functional soft materials for diverse flexible devices and a novel optical platform for soft robotics, smart wearable devices, and human-machine interaction. |
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Keywords: | durability dynamic covalent bonds mechanochromism photonic vitrimer self-healing |
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