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Strain Engineering of Metal Halide Perovskites on Coupling Anisotropic Behaviors
Authors:Yinan Jiao  Shenghui Yi  Hanwen Wang  Bing Li  Weizhong Hao  Lulu Pan  Yan Shi  Xiangyu Li  Pengfei Liu  He Zhang  Cunfa Gao  Jinjin Zhao  Jian Lu
Affiliation:1. School of Materials Science and Engineering, School of Mechanical Engineering, Shijiazhuang Tiedao University, Shijiazhuang, 050043 China;2. Centre for Advanced Structural Materials, City University of Hong Kong, Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science, 8 Yuexing 1st Road, Shenzhen Hi-Tech Industrial Park Nanshan District, Shenzhen, 518057 China

Department of Mechanical Engineering, City University of Hong Kong, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science, Tat Chee Avenue, Kowloon, Hong Kong, China;3. State Key Laboratory of Traction Power, Applied Mechanics and Structure Safety Key Laboratory of Sichuan Province, School of Mechanics and Engineering, Southwest Jiaotong University, Chengdu, Sichuan, 610031 China;4. Department of Mechanical Engineering, City University of Hong Kong, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science, Tat Chee Avenue, Kowloon, Hong Kong, China;5. State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics & Astronautics, Nanjing, 210016 China;6. College of Civil Engineering & Architecture, Zhejiang University, Hangzhou, 310058 China;7. Centre for Advanced Structural Materials, City University of Hong Kong, Shenzhen Research Institute, Greater Bay Joint Division, Shenyang National Laboratory for Materials Science, 8 Yuexing 1st Road, Shenzhen Hi-Tech Industrial Park Nanshan District, Shenzhen, 518057 China

Abstract:The power conversion efficiencies (PCEs) of the solar cells containing metal halide perovskites (MHPs) have rapidly increased and exceeded 25% during the past decade. The photovoltaic properties of these devices are extensively investigated in terms of their microstructures, environmental characteristics, and carrier dynamics, and the MHP structural evolution under high pressure is evaluated. In addition, the energy level structure, electron/hole dynamics, and optical/electronic properties of MHPs with anisotropic crystal structures are examined. However, the correlation between the structural anisotropy and material properties of these perovskites is rarely considered in the literature studies on their high-pressure behavior. In this progress report, the optical/electronic properties of MHPs with anisotropic structures under thermal, mechanically imposed, and in-service strains/stresses that have been previously neglected by researchers are summarized.
Keywords:carrier dynamics  compressive strain  metal halide perovskites  stress  tensile strain
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