| 电化学沉积法制备Co-ZnO薄膜及其室温铁磁性 |
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| 引用本文： | 张建康,贾冲,陈奕庆,朱筠清,张新华.电化学沉积法制备Co-ZnO薄膜及其室温铁磁性[J].金属功能材料,2012,19(2):23-25. |
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| 作者姓名： | 张建康 贾冲 陈奕庆 朱筠清 张新华 |
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| 作者单位： | 合肥工业大学材料科学与工程学院,合肥,230009 |
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| 基金项目： | 国家自然科学基金(103413127) |
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| 摘 要： | 摘 要:用电化学沉积方法,在锌片上成功制备出了Co掺杂ZnO稀磁半导体薄膜.XRD研究表明,Co-ZnO薄膜均为六方纤锌矿结构,没有出现与Co相关的杂质相.由XPS测量结果可知,钴离子在ZnO薄膜中以+2价的形式存在,替换了ZnO晶格中部分Zn2+.通过样品室温铁磁性测量结果进一步验证了Co2+取代了ZnO晶格中Zn2+的格位.
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| 关 键 词： | ZnO薄膜 稀磁半导体 电沉积 X射线光电子能谱分析 |
Electrodeposited Fabrication and Room Temperature Ferromagnetism of Co-doped ZnO Films |
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| ZHANG Jian-kang
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JIA Chong
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CHEN Yi-qing
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ZHU Yun-qing
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ZHANG Xin-hua.Electrodeposited Fabrication and Room Temperature Ferromagnetism of Co-doped ZnO Films[J].Metallic Functional Materials,2012,19(2):23-25. |
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| Authors: | ZHANG Jian-kang JIA Chong CHEN Yi-qing ZHU Yun-qing ZHANG Xin-hua |
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| Affiliation: | (School of Materials Science and Engineering,Hefei University of Technology, Hefei 230009,Anhui,China) |
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| Abstract: | Co doped ZnO thin films are successfully synthesized on polycrystalline Zn foils via an electrodeposition route in this paper.The XRD results show that all films are ZnO wurtzite without impurity phases.The XPS spectra show that the Co ions have a chemical valence of +2,and the doped Co2+ partially substitutes Zn2+ in ZnO lattice.Furthmore,ferromagnetism at room temperature shows Co3+ ions doped into the ZnO crystal lattices by substituting Zn2+ ions. |
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| Keywords: | ZnO thin films diluted magnetic semiconductor electrodeposition XPS |
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