| 腰果酚缩醛胺与环氧树脂的固化反应动力学的研究 |
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| 引用本文： | 杨灿,贾艳玲,程圆圆,等.腰果酚缩醛胺与环氧树脂的固化反应动力学的研究[J].粘接,2014(3):47-50. |
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| 作者姓名： | 杨灿 贾艳玲 程圆圆 等 |
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| 作者单位： | [1]华烁科技股份有限公司,湖北武汉430074 [2]催化材料科学国家民委一教育部重点实验室,中南民族大学湖北武汉430074 |
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| 摘 要： | 在不同升温速率下,用差示扫描量热分析(DSC)研究了腰果酚缩醛胺固化剂(PCD)与环氧树脂的固化反应动力学。通过Kissinger、Crane方程和等转化率的方法求得了其表观活化能E=39.89kJ/mol,固化反应级数n=0.906。
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| 关 键 词： | 腰果酚缩醛胺 环氧树脂 固化 动力学 |
Study on curing kinetics of epoxy resin cured with cardanol aldehyde-amine polymer |
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| YANG Can,JIA Yan-lin,CHENG Yuan-yuan,WU Jin-shu,ZHANG Jun-heng,ZHANG Dao-hong.Study on curing kinetics of epoxy resin cured with cardanol aldehyde-amine polymer[J].Adhesion in China,2014(3):47-50. |
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| Authors: | YANG Can JIA Yan-lin CHENG Yuan-yuan WU Jin-shu ZHANG Jun-heng ZHANG Dao-hong |
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| Affiliation: | 1 .Haiso Technology Co.,Ltd.,Wuhan,Hubei 430074,China;2.Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission ＆ Ministry of Education,South-Central University for Nationalities,Wuhan,Hubei 430074,China) |
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| Abstract: | The curing kinetics of epoxy resin/cardanol aldehyde-amine polymer system were studied scanning calorimetry （DSC） at different heating rates.The kinetic parameters such as the reaction order activation energy were solved by Kissinger equation,Crane equation and isoconversional method by differential and apparent |
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| Keywords: | cardanol aldehyde-amine polymer epoxy resin curing curing kinetics |
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