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废革屑负载Fe(Ⅲ)用于UV-Fenton法处理造纸废水
引用本文:吴超,申琳,刘一山,何强,廖学品,石碧. 废革屑负载Fe(Ⅲ)用于UV-Fenton法处理造纸废水[J]. 纸和造纸, 2010, 0(2)
作者姓名:吴超  申琳  刘一山  何强  廖学品  石碧
作者单位:四川大学轻纺与食品学院;中国农业大学食品科学与营养工程学院;四川工商职业技术学院;
基金项目:公益性行业(农业)科研专项经费(200803033); 教育部“新世纪优秀人才支持计划”(NCET-08-0367)资助
摘    要:以制革的废革屑为载体,通过固载Fe(III),制备了一种新型UV-Fenton反应的非均相催化剂(Fe-CF),并研究其对造纸废水光解氧化的催化特性。研究发现,当Fe-CF用量为0.5g·L-1,H2O2用量17mg·L-1,在光照(254nm、10W)条件下,废水光解氧化110min后其总有机碳TOC去除率达50.3%。结果表明,Fe-CF能有效促进造纸废水中木素的光解氧化及矿化,降低污染负荷,并通过改变废水成分特性,改善其生化处理性。

关 键 词:造纸废水  废革屑  非均相催化剂  Fenton反应  木素  光解氧化  

UV-Fenton Oxidation of Paper-Making Wastewater Using Fe-immobilized Leather Waste as Catalyst
WU Chao ,SHEN Lin ,LIU Yi-shan ,,HE Qiang ,LIAO Xue-pin ,SHI Bi. UV-Fenton Oxidation of Paper-Making Wastewater Using Fe-immobilized Leather Waste as Catalyst[J]. Paper and Paper Making, 2010, 0(2)
Authors:WU Chao   SHEN Lin   LIU Yi-shan     HE Qiang   LIAO Xue-pin   SHI Bi
Affiliation:WU Chao 1,SHEN Lin 2,LIU Yi-shan 1,3,HE Qiang 1,LIAO Xue-pin 1,SHI Bi 1 (1.College of Light Industry , Food Engineering,Sichuan University,Chengdu 610065 China,2.College of Food Science&Nutritional Engineering,China Agricultural University,Beijing 100083 China,3.Sichuan Technology&Business College,Dujiangyan 611830 China)
Abstract:A novel heterogeneous catalyst(Fe-CF)for Fenton reaction was prepared by immobilizing Fe(III)onto leather waste,and its catalytic activity for the UV-Fenton oxidation of wastewater from paper-making was investigated.The results indicated that the catalyst accelerated the decomposition and mineralization of lignin in the wastewater,and consequently improved the biodegradability of the wastewater.Catalyzed by Fe-CF(0.5g?L-1),TOC of wastewater was removed by 50.3%within 110 min under UV irradiation (254nm,10W)...
Keywords:paper-making wastewater  leather waste  heterogeneous catalyst  Fenton reaction  lignin  photocatalytic oxidation  
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