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Thermodynamics of Mn–Ca–j and Mn–C–j system
Authors:Zhongting Ma  Ruiming Ni  Wu Cheng
Abstract:Solubility experiments of Ca and C in Mn melts with different contents of third elements j at different temperatures were carried out in Mo-wire-heated furnace. With these data the first and second order activity interaction coefficients of j upon Ca and C, based on the same activity and the same concentration method and also In γCa0 and In γC0, were evaluated. The solubility of Ca and C in liquid Mn formulated in relation to temperature was determined and the standard free energy of solution of Ca and C in liquid Mn based on 1 wt.% solution standard was evaluated, respectively.
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