| 相转移法合成5-硝基苊 |
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| 引用本文： | 朱惠琴.相转移法合成5-硝基苊[J].化学世界,2002,43(5):259-260,254. |
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| 作者姓名： | 朱惠琴 |
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| 作者单位： | 淮阴师范学院化学系,江苏,淮安,223001 |
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| 摘 要： | 在醋酸、相转移催化剂聚乙二醇存在下 ,苊与硝酸铈铵反应生成 5 -硝基苊。反应条件温和 ,产率较高。硝酸铈铵是一种选择性良好 ,具有多方面用途的试剂。讨论了硝酸铈铵、醋酸、聚乙二醇的用量以及反应温度、时间对反应的影响。从而选出最佳反应条件
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| 关 键 词： | 硝酸铈铵 苊 聚乙二醇 |
| 文章编号： | 0367-6358(2002)05-0259-03 |
Synthesis of 5-Nitroacenaphthene by Phase Transfering Method |
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| ZHU Hui,qin.Synthesis of 5-Nitroacenaphthene by Phase Transfering Method[J].Chemical World,2002,43(5):259-260,254. |
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| Authors: | ZHU Hui qin |
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| Abstract: | In the presence of acetic acid and polyethylene glycols, acenaphthene reacts with ammonium ceric nitrate to form 5 nitroacenaphtene under mild conditions with high yields. Ammonium ceric nitrate is a reagent with good selectivity and multiple uses. The influences of the amount of ammonium ceric nitrate, acetic acid and polyethylene glycols, temperature and time upon the reaction were studied, and the optimun conditions for the reaction were found. |
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| Keywords: | ammonium ceric nitrate acenaphthene polyethylene glycols |
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