| 芳香羧酸脱羧-偶联反应研究 |
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| 引用本文： | 钟辉,吴聪,文旺,丁阳,周旭东,盛文兵. 芳香羧酸脱羧-偶联反应研究[J]. 化学试剂, 2022, 44(3): 468-476. DOI: 10.13822/j.cnki.hxsj.2022008659 |
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| 作者姓名： | 钟辉 吴聪 文旺 丁阳 周旭东 盛文兵 |
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| 作者单位： | 湖南中医药大学 药学院,湖南 长沙 410208,湖南中医药大学 药学院,湖南 长沙 410208;湖南中医药大学 中医药民族医药创新发展国际实验室,湖南 长沙 410208 |
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| 基金项目： | 湖南省自然科学基金资助项目(2021JJ30502);长沙市自然科学基金资助项目(kq2014092);国家级大学生创新创业训练计划项目(S202010541042)。 |
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| 摘 要： | 芳香族羧酸脱羧-偶联反应能够有效构建C—C或C-杂原子键,在天然活性物质、药物中间体以及特殊材料合成等方面具有重要意义,并且该方法具有很好的区域选择性、原子经济性及环境友好性等特点.近年来以芳香羧酸为基本原料的脱羧-偶联反应得到深入研究,新颖催化剂不断涌现,反应条件不断完善,为该类反应的应用提供了理论依据.从偶联反应的...
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| 关 键 词： | 芳香羧酸 脱羧-偶联反应 过渡金属催化 非金属催化 紫外光催化 低共熔溶剂 |
Study on the Decarboxylation-coupling Reaction of Aromatic Carboxylic Acid |
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| ZHONG Hui,WU Cong,WEN Wang,DING Yang,ZHOU Xu-dong,SHENG Wen-bing. Study on the Decarboxylation-coupling Reaction of Aromatic Carboxylic Acid[J]. Chemical Reagents, 2022, 44(3): 468-476. DOI: 10.13822/j.cnki.hxsj.2022008659 |
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| Authors: | ZHONG Hui WU Cong WEN Wang DING Yang ZHOU Xu-dong SHENG Wen-bing |
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| Affiliation: | (School of Pharmacy,Hunan University of Chinese Medicine,Changsha 410208,Chin;TCM and Ethnomedicine Innovation&Development International Laboratory,Hunan University of Chinese Medicine,Changsha 410208,China) |
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| Abstract: | The decarboxylation-coupling reaction of aromatic carboxylic acid can effectively construct C—C or C-heteroatomic bonds,which is of great significance in natural active substances,drug intermediates and special material synthesis,and the method is featured by good regional selectivity,atomic economy and environmental friendliness.In recent years,the decarboxylation-coupling reaction with aromatic carboxylic acid has been deeply studied,and many novel catalysts are constantly emerging,providing a theoretical basis for the application of such reactions.In order to provide a meaningful reference for further research,coupling reaction type,mechanism and the different transition metal catalysts are summarized in this mini-review. |
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| Keywords: | aromatic carboxylic acids decarboxylation-coupling reaction transition metal catalysis non-metal catalysis UV photocatalysis deep eutectic solvents |
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