UPTAKE OF METAL IONS BY A NEW CHELATING ION-EXCHANGE RESIN. PART 5 : THE EFFECT OF SOLUTION MATRIX ON ACTINIDES

ABSTRACT

The influence of commonly occurring matrix constituents on the uptake of representative actinides in the tri-, tetra-, and hexavalent oxidation states by a new chelating ion exchange resin, called Diphonix?, has been investigated. The effect of increasing concentrations of HF at three fixed HC1 concentrations on the retention of U(VI), Np(IV), and Am(III) was measured. All three actinides showed strong retention in HF even up to a concentration of 1 M The effect of sulfuric, oxalic and phosphoric acids at three fixed HNO₃ concentrations on the retention of Th(IV), U(VI), and Am(III) was also measured. Only when the concentration of the complexing acids was above 0.1 M was the retention of the actinides decreased significantly at 0.1 M HNO₃ The effect was much less pronounced at higher HNO₃ concentrations.

Sodium, calcium, aluminum and iron were selected to study the influence of cationic matrix constituents on the uptake of actinide ions by Diphonix. In the case of tetra- and hexavalent actinides (represented by Th and U, respectively) only the very highest concentrations of Fe(III) and Al(III) caused a significant decrease in the retention of the two higher valent actinides. On the other hand, Am(III) retention was significantly lowered by Al and Fe(III) concentrations above 10^?2 M The influence of Al and Fe(III) on the uptake of Am(III) may be minimized by use of fluoride ion to complex Al and by reducing Fe(III) to Fe(II). Macroconcentrations of sodium and calcium had only minimal influence on the uptake of actinides in all three oxidation states.