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Olive residues (cuttings and kernels) rapid pyrolysis product yields and kinetics
Affiliation:1. Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, China;2. Centre for Simulation and Modelling of Particulate Systems, Southeast University — Monash University Joint Research School, Suzhou 215123, China;3. Department of Chemical Engineering, Monash University, Clayton, Victoria 3800, Australia
Abstract:A study of pyrolysis of olive residues (cuttings and kernels) at a temperature range from 300 to 600°C, has been carried out. The experiments were performed in a captive sample reactor at atmospheric pressure under helium. The yields of the derived gases, pyrolytic liquids and char were determined in relation to pyrolysis temperature, at heating rates of about 200°C/s.As the pyrolysis temperature was increased the percentage mass of char decreased whilst gas and oil products increased. The oil products increased to a maximum value of ∼30 wt% of dry biomass at about 450–550°C. The major gaseous products are CO and CO2.A simple first order kinetic model has been applied to the evolution of total losses and gases. Kinetic parameters have been estimated and compared with other reported similar data.
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