Affiliation: | 1. Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak, Malaysia
Contribution: Conceptualization (lead), Formal analysis (lead), Investigation (lead), Methodology (lead), Writing - original draft (lead);2. Department of Chemical, Polymer & Composite Materials Engineering, University of Engineering & Technology Lahore, New Campus, Lahore, Pakistan
Contribution: Supervision (supporting), Writing - review & editing (supporting);3. Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak, Malaysia
Centre of Research in Ionic Liquids (CORIL), Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak, Malaysia
Contribution: Supervision (supporting);4. Department of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak, Malaysia |
Abstract: | Nanocellulose, which is biodegradable and possesses excellent physicochemical properties, has high potential in many applications. However, its intrinsic hydrophilic nature makes it difficult to be used as fillers in most hydrophobic polymer composites. Here, cellulose nanocrystals (CNCs) were successfully prepared using 1-hexly-3-methylimidazolium hydrogen sulfate Hmim]HSO4] ionic liquid under optimized conditions at 71°C, ultra-sonication amplitude of 69%, and ultrasonication time of 23 min. The prepared CNCs were surface-modified using 1-butyl-3-methylimidazolium tetrafluoroborate Bmim]BF4]. A 3D printable nanocomposite filament containing CNCs embedded in polylactic acid was fabricated via extrusion process at 170°C. The prepared filaments were characterized using universal testing machine, field emission scanning electron microscopy, thermogravimetric analysis, and FTIR. It was shown that CNCs had a diameter and length of 10–24 and 60–400 nm, respectively. It was also found that incorporating 2 wt% of CNCs into the matrix phase increased filaments tensile strength by 2.5% (from 54.59 to 57.35 MPa) due to the plasticization effect of Bmim]BF4]. The prepared composites exhibited lower activation energies compared to neat PLA due to the small traces of sulfate group on F-CNC. The mechanical attributes of CNCs/PLA nanocomposites were retained at values comparable to that of fresh PLA and were demonstrated to be 3D printable. |