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Influence of firing temperature on the color developed by a (Zr,V)SiO4 pigmented opaque ceramic glaze
Affiliation:1. Departamento de Engenharia Mecânica, Centro Tecnólogico, Universidade Federal de Santa Catarina, Caixa Postal 476, Campus Universitário, Trindade 88040-900, Florianópolis, Brazil;2. Dipartimento di Ingegneria dei Materiali e dell’Ambiente, Università degli Studi di Modena e Reggio Emilia, Via Vignolese 905, 41100 Modena, Italy;3. Dipartimento di Scienze e Metodi dell’Ingegneria, Università degli Studi di Modena e Reggio Emilia, Via Fogliani 1, 42100 Reggio Emilia, Italy;4. Departamento de Engenharia de Minas, Centro de Tecnologia, Universidade Federal do Rio Grande do Sul, Caixa Postal 15021, 91501-970 Porto Alegre, Brazil;1. LEAM, University of Jijel—B.P 98 Ouled Aissa, 18000 Jijel, Algeria;2. National Research Council, IDPA, Section of Milan—Via Botticelli 23, I-20133 Milan, Italy;3. European Synchrotron Radiation Facility, 71 Avenue des Martyrs, 38000 Grenoble, France;4. LIME, University of Jijel—B.P 98 Ouled Aissa, 18000 Jijel, Algeria;1. School of Materials Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen, 333001, PR China;2. State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, 100084, Beijing, PR China;3. Materials Engineering, The University of Queensland Brisbane, St Lucia, QLD 4072, Australia;1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China;2. Dongguan Wonderful Ceramic Industry Co., Ltd., Dongguan 523281, China
Abstract:The analysis of the physical interactions between pigments, opacifiers and glazes is fundamental to understand the optical behavior of ceramic glazes. Furthermore is important to verify if the glaze devitrifies because the crystallized phases can contribute to the optical properties of the system. The size and the quantity of the formed crystals can change significantly the glaze color. The mean goal of this study was to evaluate the influence of firing temperature on the color stability of an opaque ceramic glaze colored by a blue vanadium–zircon pigment taking into account all the optical components. Quantitative X-ray diffraction analysis was conducted in order to evaluate the pigment dissolution at the three studied temperature and the quantity of the in situ formed zircon crystals from the used frit. The reported study demonstrated the importance to consider all the components in a multicomponent optical system as a ceramic glaze.
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