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Reaction sintering of β-tricalcium phosphates and their mechanical properties
Affiliation:1. National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Shimo-shidami, Moriyama-ku, Nagoya 463-8560, Japan;2. Faculty of Engineering, Chiba Institute of Technology, 2-17-1, Tsudanuma, Narashino-shi, Chiba 275-0016, Japan;1. Centre for Nanoscience and Technology, Pondicherry University, Puducherry, 605 014, India;2. Department of Metallurgical Engineering, Indian Institute of Technology (Banaras Hindu University), Varanasi, 221005, India;1. A.A. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991 Moscow, Russian Federation;2. M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;1. Materials Science Division, Department of Physics, The University of Burdwan, Golapbag, Burdwan 713104, West Bengal, India;2. Surface Physics and Materials Science Division, Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700064, India;1. Department of Materials and Ceramics Engineering, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal;2. UIDM, ESTG, Polytechnic Institute of Viana do Castelo, 4900 Viana do Castelo, Portugal;3. RMS Foundation, Bischmattstrasse 12, CH-2544 Bettlach, Switzerland;1. Department of Ceramics and Glass Engineering, University of Aveiro, CICECO, 3810-193 Aveiro, Portugal;2. UIDM, ESTG, Polytechnic Institute of Viana do Castelo, 4900 Viana do Castelo, Portugal
Abstract:Various kinds of calcium oxides, carbonates and phosphates were used as the raw materials, and β-TCP ceramics was fabricated by reaction sintering at 1100 °C, and the sinterability, the reaction sintering behavior and mechanical properties of reaction-sintered β-TCP were investigated. Reaction-sintered bodies using CaHPO4 + HAp consisted of single β-TCP phase, and bulk density and bending strength increased with extending sintering time. On the contrary, normal-sintered β-TCP synthesized using CaHPO4 + HAp did not change in bulk density and bending strength with extending sintering time. Reaction-sintered body using CaHPO4 + HAp as the raw materials showed higher bulk density and bending strength than normal sintered β-TCP.
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