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The Actual Active Species of Sulfur‐Modified Gold‐Supported Palladium as a Highly Effective Palladium Reservoir in the Suzuki–Miyaura Coupling
Authors:Naoyuki Hoshiya  Satoshi Shuto  Mitsuhiro Arisawa
Abstract:The actual active species of the recently developed sulfur‐modified, gold‐supported palladium material, S ‐modified A u‐supported Pd (SAPd), with one of the lowest Pd‐releasing levels and high recyclability in the Suzuki–Miyaura coupling, was investigated. Also, SAPd was found to work repeatedly as an excellent Pd reservoir for liquid‐phase combinatorial synthesis.
Keywords:C?C coupling  combinatorial chemistry  green chemistry  heterogeneous catalysis  palladium
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