The synthesis of carbon nanotubes at low temperature via carbon suboxide disproportionation |
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Authors: | Mingwang Shao |
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Affiliation: | Structure Research Laboratory and Department of Chemistry, University of Science and Technology of China, Hefei 230026, People’s Republic of China |
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Abstract: | Carbon nanotubes were synthesized via a novel route using an iron catalyst at the extremely low temperature of 180 °C. In this process, carbon suboxide was used as carbon source, which changed to freshly formed free carbon clusters through disproportionation. The carbon clusters can grow into nanotubes in the presence of Fe catalyst, which was obtained by the decomposition of iron carbonyl Fe2(CO)9 at 250 °C under nitrogen atmosphere. The products were characterized with XRD, TEM, HRTEM and Raman spectroscopy. |
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Keywords: | A. Carbon nanotubes, vapor growth carbon B. Catalyst |
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