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Platinum(VI) dihydroxo tetramesitylporphyrin; characterization and chemical reactivity |
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| Authors: | Nasser Safari Saeed Rayati Akbar Ghaemi Farzad Bahadoran Hamid Reza Khavasi |
| Affiliation: | aDepartment of Chemistry, Shahid Beheshti University, G. C., Evin, Tehran 1983963113, Iran;bDepartment of Chemistry, K.N. Toosi University of Technology, P.O. Box 16315-1618, Tehran 15418, Iran |
| Abstract: | Tetramesitylporphyrin platinum(VI) dihydroxo complex, TMPPt(OH)2 · 2 benzoate was synthesized by addition of two equivalent of meta-chloroperbenzoic acid molecules to the tetramesitylporphyrin platinum(II). This complex was characterized by X-ray diffraction and spectroscopic methods, and is capable to convert two molecules of triphenylphosphine to triphenylphosphine oxide. |
| Keywords: | Platinum(VI) dihydroxo Oxidation Cytochrome P-450 Triphenylphosphine meta-Chloroperbenzoic acid |
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