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UV-Fenton方法处理偏二甲肼废水
引用本文:贾瑛,李毅,张秋禹.UV-Fenton方法处理偏二甲肼废水[J].含能材料,2009,17(3):365-368.
作者姓名:贾瑛  李毅  张秋禹
作者单位:1. 西安高技术研究所503室,陕西,西安,710025;西北工业大学理学院,陕西,西安,710072
2. 西安高技术研究所503室,陕西,西安,710025
3. 西北工业大学理学院,陕西,西安,710072
摘    要:利用UV-Fenton方法处理偏二甲肼(UDMH)废水,以废水中UDMH和化学需氧量(COD)的去除率为检测指标,通过正交实验确定了反应的主要影响因素以及最佳工艺组合,并比较研究了五种反应体系的降解情况,初步探讨了中间产物的变化规律.实验结果表明:常温下,H2O2为1.5 Qth(theoretical quantity),pH值在3.5左右,Fe2+与H2O2的摩尔比为110时,经过45 min的UV-Fenton氧化降解,UDMH废水(400 mg/L)中UDMH去除率可达到99%以上,COD去除率可达到95.8%.

关 键 词:环境工程  UV-Fenton法  偏二甲肼(UDMH)废水  COD去除率
收稿时间:2008/10/7 0:00:00
修稿时间:2009/2/10 0:00:00

Degradation of Unsymmetrialdimethy Hydrazine Wastewater by UV-Fenton Process
JIA Ying,LI Yi and ZHANG Qiu-yu.Degradation of Unsymmetrialdimethy Hydrazine Wastewater by UV-Fenton Process[J].Chinese Journal of Energetic Materials,2009,17(3):365-368.
Authors:JIA Ying  LI Yi and ZHANG Qiu-yu
Affiliation:1.Section 503;Xi'an High Technique Institute;Xi'an 710025;China;2.Northwestern Polytechnical University;Xi'an 710072;China
Abstract:UV-Fenton process was applied to oxidize the unsymmetrialdimethy hydrazine(UDMH) wastewater.The optimal manufacturing process and the primary factors contribute to the UV-Fenton oxidation were determined by orthogonal experiments with removal efficiencies of the UDMH and COD in wastewater as two main monitor index,and the removal efficiencies of UDMH wastewater of five kinds of reaction systems were compared.Results show that when initial H2O2 is 1.5 times of the theoretical quantity(1.5 Qth),the molar rati...
Keywords:enviromental engineering  UV-Fenton process  unsymmetrialdimethy hydrazine(UDMH) wasterwater  COD removal efficiency
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