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棉织物无氟超疏水整理
引用本文:高琴文,刘玉勇,朱泉,郭玉良. 棉织物无氟超疏水整理[J]. 纺织学报, 2009, 30(5): 78-81
作者姓名:高琴文  刘玉勇  朱泉  郭玉良
作者单位:东华大学生态纺织教育部重点实验室,上海,201620
基金项目:长江学者与创新团队发展计划 
摘    要:针对含氟拒水剂不环保的缺点,采用无氟溶胶-凝胶法赋予棉织物疏水性能。先浸轧二氧化硅溶胶,再将烷烃硅氧烷自组装到棉织物上,成功制备了具有超疏水性能的棉织物。通过控制催化剂用量,制备不同粒径的二氧化硅溶胶,并讨论了溶胶粒径、烷基硅氧烷结构和浓度及皂洗次数对接触角的影响。采用这种方法整理后棉织物与水的接触角可达到155°。利用扫描电子显微镜观察二氧化硅溶胶整理前后棉织物的表面形态并对性能进行测试,结果表明整理前后棉织物的物理机械性能变化较小。

关 键 词:棉织物  溶胶-凝胶法  无氟  超疏水  整理
收稿时间:1900-01-01;

Non-fluorinated superhydrophobic finish of cotton fabric
GAO Qinwen,LIU Yuyong,ZHU Quan,GUO Yuliang. Non-fluorinated superhydrophobic finish of cotton fabric[J]. Journal of Textile Research, 2009, 30(5): 78-81
Authors:GAO Qinwen  LIU Yuyong  ZHU Quan  GUO Yuliang
Affiliation:Key Laboratory of Eco-Textiles;Ministry of Education;Donghua University;Shanghai 201620;China
Abstract:The aim of this study is to prepare water repellent cotton fabric via sol-gel method using non-fluorinated additives,thus avoiding the potential risk for environment from fluoroalkyl compounds.Superhydrophobic cotton fabric was successfully obtained first by dip-coating the silica sol,then the fabric was modified with alkyltrialkoxysilanes through self-assembly methods.Silica sols with different sizes were prepared by controlling the concentration of ammonia.The influence of silica nanoparticle sizes,struct...
Keywords:cotton fabric  sol-gel method  non-fluorinated  superhydrophobic  finishing  
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