Addition of sec-butyllithium to m-diisopropenylbenzene |
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Authors: | G.Gordon Cameron Gavin M. Buchan |
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Affiliation: | Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen AB9 2UE, UK |
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Abstract: | The reaction of equivalent quantities of sec-butyllithium with m-diisopropenylbenzene in cyclohexane and benzene solution in the presence and absence of catalytic amounts of triethylamine, does not yield the diadduct quantitatively. Oligomer formation occurs to varying extents depending on the reaction conditions, and, contrary to claims in the literature, this may not be a good route to a difunctional initiator for anionic polymerization. |
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Keywords: | To whom correspondence should be addressed |
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