Hydrothermal Synthesis and Low-Temperature Sintering of Zinc Gallate Spinel Fine Particles |
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Authors: | Masanori Hirano Naoshi Sakaida |
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Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Aichi Institute of Technology, Yakusa, Toyota 470–0392, Japan |
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Abstract: | Nanosized powders of single-phase zinc gallate (ZnGa2O4) spinel were hydrothermally synthesized from solutions in the presence of NaOH over the pH range of 1.9 to 7.0 and from solutions above pH 7.0, i.e., the very basic medium (pH of 13.85), by removing the residual ZnO phase by washing with aqueous H2SO4 from the precipitate mixtures of zinc gallate spinel particles and ZnO. A very wide compositional range (Zn/2Ga = 0.705–1.157) of zinc gallate spinel solid solutions could be hydrothermally synthesized in the form of nanosized particles from acid and very basic mediums (pH of 2.4–13.85) in the presence of NaOH. These hydrothermally synthesized spinel powders showed good sinterability and almost full densification at 1100°C for 1 h. Dense sintered bodies consisting of single-phase zinc gallate spinel were fabricated at 1100°C using zinc gallate spinel powders having almost stoichiometric composition formed from the solution at pH 9.95 in the presence of aqueous ammonia. |
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Keywords: | thermal treatment spinels zinc gallium/gallium compounds sinter/sintering |
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