Study of the relation between the phosphorus content of coal and coke

Established methods for the determination of phosphorus in coal and coke were compared and found to give results in satisfactory agreement. The method for the determination of phosphorus described in BS 1016, ‘Methods for the analysis and testing of coal and coke’, Part 9, 1977 was used to study the relation between the phosphorus content of coals and their corresponding cokes. The cokes were prepared on laboratory, test oven and industrial scales, by the carbonization of various bituminous coals within the range of volatile matter yield of 16–40 wt%. The determined values of the phosphorus contents of these cokes and their parent coals indicated that the phosphorus present in the coal is completely retained in cokes carbonized to temperatures between 900 and 1050 °C. On the basis of these experimental results it is suggested that the phosphorus content of coke can generally be calculated from a knowledge of the phosphorus content of the coal and the coke yield with an accuracy which is sufficient for normal requirements.