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Friction-induced physical and chemical interactions among diamond-like carbon film,steel ball and water and/or oxygen molecules
Affiliation:1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China;2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China;1. Department of Physical Metallurgy and Materials Testing, Montanuniversität Leoben, Franz-Josef-Str. 18, 8700 Leoben, Austria;2. Teer Coatings, Berry-Hill-Industrial-Estate, West Stone House, Droitwich, Worcestershire, WR9 9AS, United Kingdom;3. Materials Chemistry, RWTH Aachen University, Kopernikusstr. 10, D-52074 Aachen, Germany;4. Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstr. 400, D-01328 Dresden, Germany;5. MIBA High Tech Coatings, Dr.-Mitterbauer-Str. 3, 4655 Vorchdorf, Austria;1. Key Laboratory of Science and Technology on Wear and Protection of Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;1. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China;2. School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;3. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;4. Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China;1. Tribology Research Institute, State Key Laboratory of Traction Power, Southwest Jiaotong University, Chengdu 610031, China;2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;3. Beijing Key Laboratory of Long-life Technology of Precise Rotation and Transmission Mechanisms, Beijing Institute of Control Engineering, Beijing 100094, China
Abstract:Friction and wear behaviors of diamond-like carbon (DLC) film sliding against steel ball were investigated on a ball-on-disk test rig at different relative humidity (RH) in a nitrogen environment. The worn surface morphology of the steel ball was observed on a scanning electron microscope (SEM), while the chemical states of some typical elements on the worn surface of DLC film were investigated by means of X-ray photoelectron spectroscopy (XPS). The result showed that the DLC film recorded continuously increased friction coefficient and wear rate with increasing relative humidity from 5% to 100%. In dry nitrogen (RH < 5%), thick and compact transferred carbon-rich layer was observed covering on the worn surface of steel ball, while the chemical states of the original and worn film surface showed no obvious change. In humid nitrogen, distinct changes of the chemical states on the worn surface of DLC film took place, indicating that tribochemical reactions such as the oxidation of DLC film and the interactions between DLC film and steel ball were involved in the friction process. Therefore, it was proposed that the friction and wear behaviors of DLC film were dependent on the friction-induced physical and chemical interactions among DLC film, steel ball and water and/or oxygen molecules. The roles of environment in the friction and wear behaviors of DLC film were discussed in terms of the friction-induced physical and chemical interactions.
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