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环保型水性聚氨酯真皮涂饰剂应用研究
引用本文:蔡福泉,万灵书. 环保型水性聚氨酯真皮涂饰剂应用研究[J]. 皮革化工, 2011, 0(4): 10-11,15
作者姓名:蔡福泉  万灵书
作者单位:温州市登达化工有限公司;浙江大学高分子科学研究所;
摘    要:以聚有机硅氧烷为改性剂,采用预聚、扩链改性及中和乳化技术制备了高性能环保型水性聚氨酯真皮涂饰剂。研究了改性聚氨酯涂层的表面化学组成、表面疏水性以及表面干/湿擦牢度等性能。实验结果表明,所制备的乳液能稳定存在1年以上,由于聚有机硅氧烷的引人以及成膜过程中原位交联的实现,制得的聚氨酯涂层具有疏水性好、干/湿擦牢度高的特点。

关 键 词:聚氨酯  真皮涂饰剂  聚有机硅氧烷  表面性能

Properties of Waterborne Polyurethane Latex for Environmental Friendly Leather Finishing Agent
CAI Fu-quan,WAN Ling-shu. Properties of Waterborne Polyurethane Latex for Environmental Friendly Leather Finishing Agent[J]. Leather Chemicals, 2011, 0(4): 10-11,15
Authors:CAI Fu-quan  WAN Ling-shu
Affiliation:CAI Fu-quan1,WAN Ling-shu2(1.Wenzhou Dengda Chemical Co.Ltd,Wenzhou 325000,China,2.Institute of Polymer Science,Zhejiang University,Hangzhou 310027,China)
Abstract:Environmental friendly leather finishing agent based on polyurethane has attracted great attention in recent years.In this paper we reported the synthesis of polyurethane latex through pre-polymerization,chain extension,neutralization and emulsification using organic siloxane polymer as the modifier.The surface composition,surface hydrophilicity,and mechanical properties were investigated.The results indicated that the resultant latex could be stored up to one year.Furthermore,due to the introduction of org...
Keywords:polyurethane  leather finishing agent  organic siloxane polymer  surface properties  
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