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以TEOS为硅源的聚硅硫酸铁制备与除藻性能
引用本文:郑怀礼,谢礼国,高旭,谭红芳,杨波,吉方英.以TEOS为硅源的聚硅硫酸铁制备与除藻性能[J].土木与环境工程学报,2009,31(6):102-106.
作者姓名:郑怀礼  谢礼国  高旭  谭红芳  杨波  吉方英
作者单位:重庆大学,三峡库区生态环境教育部重点实验室,重庆,400045
基金项目:国家自然科学基金,重庆市重点科技攻关项目,教育部高等学校科技创新工程重大项目培育资金项目 
摘    要:采用正硅酸乙酯(TEOS)代替传统的硅酸钠制备活性硅酸,将活性硅酸与聚合硫酸铁反应合成聚硅硫酸铁混凝剂,并研究了相关机理。由于正硅酸乙酯水解很缓慢,容易控制,可以得到重现性好的产物,有利于进行除藻性能的研究。通过正交实验等研究获得了聚硅硫酸铁的优化合成条件,即铁硅摩尔比为1.0,反应温度为50℃和反应时间为60min。论文还研究了优化条件下合成的聚硅硫酸铁混凝剂除藻性能,得到除藻优化条件,即原水的pH值为11.0、预氧化剂的投加量为0.70mg/L,聚硅硫酸铁的投加量为24.1mg/L。

关 键 词:聚硅硫酸铁  除藻  水处理  正硅酸乙酯
收稿时间:2009/5/10 0:00:00

Preparation of Poly ferric Silicate Sulfate(PFSS)from Tetraethylorthosilicate and Its Algae Removal Performance
ZHENG Huai li,XIE Li guo,GAO Xu,TAN Hong fang,YANG Bo and JI Fang ying.Preparation of Poly ferric Silicate Sulfate(PFSS)from Tetraethylorthosilicate and Its Algae Removal Performance[J].Journal of Civil and Environmental Engineering,2009,31(6):102-106.
Authors:ZHENG Huai li  XIE Li guo  GAO Xu  TAN Hong fang  YANG Bo and JI Fang ying
Affiliation:(Key Laboratory of the Three Gorges Reservoir Region's Econ-Environment, Ministry of Education, Chongqing University Chongqing 400045, P. R. China)
Abstract:Poly-ferric silicate sulfate flocculants were prepared by using tetraethylorthosilicate and poly-ferric sulfate as raw materials. The relevant mechanism was studied. And it was found that since tetraethylorthosilicate had the characteristics of slow hydrolyzation, the reaction was easy to control. Thus, the products had a good repeatability, which was better for the study of algae removal. The optimum preparation conditions of poly-ferric silicate sulfate were determined by using orthogonal design, in which Fe/SiO_2 mole ratio was 1, polymeric temperature was 50℃ and polymeric time was 60 minutes. Furthermore, the optimum conditions of removals algae were determined as well, in which when the pH of raw waste water was 11.0, the dosage of PFSS prepared in the optimum condition was 24.1mg/L and the dosage of pre-oxidation was 0.7mg/L.
Keywords:poly-ferric silicate sulfate flocculants  algae removal  Water Treatment  tetraethylorthosilicate(TEOS)
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