Studies on PVA/AgI-based polymeric membranes for exploration of antibacterial activity

In the present communication, solid polymer electrolyte films have been prepared using solution cast technique based on polyvinyl alcohol (PVA) as host polymer and silver iodide (AgI) as salt. The objective of the study is to develop PVA electrolytic films with AgI and evaluate to protect against simulants of biological warfare agents. The antibacterial activities of the films are explored against Aeromonas hydrophila, Escherichia coli, Salmonella typhii, and Shigella boydii. The antibacterial effects of the PVA/Ag⁺ hybrids were assessed by the minimum inhibitory concentration method. Polymer electrolyte films show good antibacterial activity against A. hydrophilla, S. typhii, and S. boydii. Scanning electron microscopy is used to study the surface morphology of the polymeric membranes. Complex impedance spectroscopy is used for characterizing the electrical and dielectric properties of the electrolyte samples. Frequency-dependent various dielectric properties such as dielectric constant, dielectric loss, and loss tangent have been discussed. The variations of AC conductivity gives the explanation in understanding the mechanism of the ion transport and determine power exponent value n lying in the range 1 and 1.2 which represents the trapping of ions in the polymer matrix.