Effect of A-site metal on methane combustion on 2% Pd / AMn1-x
Fe
x
O3 (A = Ba, La, Pr; x = 0.4, 0.6, 1) perovskites |
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Authors: | Markus J Koponen Tapani Venäläinen Mika Suvanto Kauko Kallinen Toni-J J Kinnunen Matti Härkönen Tapani A Pakkanen |
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Affiliation: | (1) Department of Chemistry, University of Joensuu, P.O. Box 111, FI 80101 Joensuu, Finland;(2) Typpitie 1, Ecocat Oy, FI, 90650 Oulu, Finland |
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Abstract: | Barium, lanthanum, and praseodymium perovskites were prepared by malic acid complexation. Surface areas of the La and Pr perovskites
were between 17.1 and 21.6 m2 g−1. The moderate low surface areas (5.7 m2 g−1) observed for corresponding barium perovskites were due to the high calcination temperatures. The calcination temperature
also affected the shapes and sizes of the perovskite particles. According to SEM images the nanoparticles of the La and Pr
perovskites were spherical, whereas those of barium perovskites were flakes. The conversion of methane increased in the order
of A-site metal Ba < Pr < La. The CH4 conversion after SO2 treatment correlated with size of the perovskite particles: the smaller the particles the better the activity. The highest
methane conversion after SO2 treatment was achieved with lanthanum perovskite with B-site metal combination Mn0.4Fe0.6. |
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Keywords: | perovskite methane combustion SO2 poisoning |
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