Determination of molecular weight averages and molecular weight distribution by g.p.c. of N-trifluoroacetylated polyamides |
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Authors: | Klaus Weisskopf |
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Affiliation: | Institut für Physikalische Chemie der Universität Mainz und Sonderforschungsbereich 41, Chemie und Physik der Makromoleküle, Sektion Mainz, West Germany |
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Abstract: | To determine their molecular weight averages and molecular weight distribution, N-trifluoroacetylated (TFA) polyamides are studied using gel permeation chromatography in tetrahydrofuran at 25°C. Several calibration methods (calibration with polydisperse standards, universal calibration) are tested; among these, direct calibration of Mw of polydisperse samples vs. peak maximum of the corresponding g.p.c. chromatogram leads to the best results. Calculated molecular weight averages of nylon 6-TFA and TrogamidR-TFA are compared with data from light scattering, viscometry and osmometry. |
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Keywords: | polyamides gel permeation chromatography calibration methods |
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